Kinetic Equations of Free-Radical Nonbranched-Chain Processes of Addition
نویسندگان
چکیده
منابع مشابه
Kinetic Studies of Some Free Radical Reactions
Kinetic and mechanistic studies on some characteristic freeradica1 reactions are reviewed briefly. The unimolecular rearrangements: RCMe2CH ÷ Me2CCH2R, fall into two classes. Class 1: R = R'C(O)O for which the 1,2—migration occurs via a 5—eenter cyclic transition state with considerable charge separation, [R'C02 Me2CCH2]*. Class 2: R = H2C=CH, Me3CC=0, C6H5, Me3CCsC, and CsN, for which migratio...
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ژورنال
عنوان ژورنال: European Chemical Bulletin
سال: 2018
ISSN: 2063-5346
DOI: 10.17628/ecb.2018.7.123-142